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You can't "Colorize" an empty transparent layer with this tool
instead colorize directly the layer below (your picture), or use the bucket tool or the gradient tool to "colorize" -> fill an empty layer
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I’ve seen that greenish tint before when converting to B/W. What usually fixes it for me is going to Colors → Desaturate → Desaturate or using Colors → Color to Gray instead of just dropping saturation. If the tint still hangs around, a quick tweak in Colors → Color Balance (push midtones a bit toward magenta) clears it up.